Mitsubishi MR-508CL Manuel d'utilisateur

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Page 1 - INTRODUCTION

1 (10)Chapter-1INTRODUCTIONi

Page 2 - 'primaries'

1 (18)19.-Oxo-Thio-Oxo-Oxo-H-H-5,5'-bis(»ethine)barbi-turlcacidandietalcotp1exesTonscryst.dyeaggregateswithcya¬nineions.Alsoundergointer10I.solid

Page 3 - Interest

1 (19)mNaphtholactai63,7GLightandsublimationfastdyes-3-chlorophe--SubstitutedNaphtholac-nyl;lethyl;tairesidueethyl;phenyl-Oxo-Ethyl-phenyl25.-Oxo-Oxod

Page 4 - Important

1 (20)Producesfast,deep,clearyellowshadesonPVCYellow-H-Substitutedaiinoiethylquinolones31.-Oxo-Oxo-Oxo-HHonoazo-dyes71YellowAzodyes72V.-Oxo-OxoExhibit

Page 5 - Literature

1 (21)Table2*ThlobarbituricAcid&derivativesRiA/RuN5R3R14R2Ref.UsesColourandSpectraldataPropertiesRRS.RNo.Fluorescent79HerocyanlnesAiax(HeOH)=560na

Page 6

1 (22)6.-Thio-OxoCyanine486,87Herocyaninedyes-Oxo-EthylUsefulassensitizersinS-andku-sensitizedsilverbrosolodideeiulsions-Ethyl-fun)substitutedbenzo-py

Page 7 - "Cl

1 (23)Table3*TrlarainoandTetraamlnoPyrimidine&derivatives1\31R2R3S.RUsesColourandSpectraldataRRef.PropertiesNo.1.-H-(un)substltuted-HailnoHairdye-

Page 8 - H2O):410

1 (24)93AzodyesUsefulfordyeingofcelluloslctex¬tilesandpaper.Alsogivesstoragestableconed,dye30lns.-4-<6-iethyl-7-sulfo-Aiino2-benzothlazolyl)-phenyl

Page 9 - -Substituted-p-Aiino-a2o

1 (25)3.AhairdyecoipositionisiadewithResorcinolascouplerandTetraaiinopyriiidineasdeveloperwith3%H2O2atpH10.5,dyeshuianhairred-brounwithgoodcolourinten

Page 10 - Produces

1 (26)7,Ahairdyecompos!tIonisaadewith7-hydroxy-4-Be-couaarlnandp-aalno-phenolascouplerandTetraaaino-pyriaidlnederivs.asdeveloperswithaixt.offattyales,

Page 11 - Honoazo

1 (27)Table4i2»4-J>iamlno-pyrlmldlne&derivatives3R31R2R3s.RRUsesColourandSpectraldataPropertiesRef.No.1.-Ailno-Ailno-p-broiopheny1azo-p-ethoxyp

Page 12 - -Substituted

1 (11)Adyeisacolouredsubstancethatcanbeappliedinsolutionordispersiontoasubstrate,thusgivingitacolouredappearance.Dyesmaybeclassifiedaccordingtoeithert

Page 13 - Thlobarbitur

1 (28)3.-A«ino-Aiino-2-(4-aiinophenyl--Hydroxyazo)-6-Bethyl-7-benzothiazolesulfonicacid-Yellow.X(H20K413n>Producesyellowshadesonpaper.leatherfc-OHo

Page 14 - Herocyamne

1 (29)Table5:4,6-DlamlnopyTinidlne&derivativesR±32SR31R2R3S.RRPropertiesUsesColourandSpectraldataRef.'No,1.-3-(7-dialkyla«i--Aiinono)couiarin

Page 15 - Properties

1 (30)YellowPolyaencdyes134Producesgoldenyellowprintingsandcontinuousdyeingsonpolyesterandcottonfabricswithgoodfastnesstolight,heatandwater-[[2-(acryl

Page 16 - H2C>2

1 (31)-Substitutedphenyl-Ailnoorheterocyclylazo12.-Ethylthlo-AilnoProducesbrightyellowtoredshadesonpolyesterfibresYelloworRedDisperseazo142dye13.-Ethy

Page 17 - Tetraaiino

1 (32)andderivativesTable6:HalogenatedpyrimidinesColour&UsesRef.PropertiesRZYXBAS.GeneralforaulaspectralNo.data-HReactivea20dye157YellowProducesli

Page 18 - 7-hydroxy-4-Be-couaarln

1 (33)-OptionallyProducesbluishRed-substitutedredshadesonscarletcottonReactivedi;ortrifluo—Bridgingropyri*idinyl-groupordichloro,difluoropyriiidinyl16

Page 19 - -p-broiophenylaiino

1 (34)!Producesfastgreenishyellowshalesoncot-fellow-alkalicleava--2,6-dlMuoro-S—Directbond;-lunlsubsh-bleCH:CM;groupReactive167,168,9.CX02SZ]1.2ACZM-C

Page 20 - -6-Bethyl

1 (35)YellowReactive175.233azodyes173Producesgree¬nishyellowshadesoncottonfabrics-Bridginggroup-2.4-dichloro-5-cyano-6-pyri-5-chlor0-2.4-difluoro-6-py

Page 21 - -(un)substituted

1 (36)1.Producesfast1.Yellow2.Red*-»ax=530niReactive-CMfoaopho-ncresidue-H-2,4-dichloro-•5-fonyl-6-pyriaidinyl,2-chloro-4-HM1chloroethylsul-fonyl)ethy

Page 22

1 (37)-BridgingproducesclearBlue-(un)substitu-blueshadesonX.tedCi-6alkyl,cottoncycloaIky1,aryl,aralkyl-HReactive-2,4-difluoro-S-chloro-6-pyrliidinyl20

Page 23 - -NH.CH2CH20H

1 (12)limitationsledtotheThese1ndustrles.cosraetlcnewintermediatesanddyes,andintroductionofsometoxicdyestuffintermediates*Certainreplacementforthemole

Page 24 - B+S02YK(

1 (38)24.(XRNYS(0)(|_2Z)AtB]A-Benzene.Naph-[2S(O)j_2KYRX]0_jthaleneorheterocyclicradicalsop¬tionallycontg.addnl,azogroup-Substitutednaphthalenesulfoni

Page 25 - -2,4-difluoro-5

1 (39)28.A2S(O)0_2CH2CH2NRX-Org.dyeradical-5-chloro-2,4-difluoro-pyri-aidlnylailno-Directbondorbridging-(unisubstitu¬tedCi_4alkyl,oncottonC2-6-alkylen

Page 26 - '£02ÿ0.5-1.5

1 (40)249,253BlueReactivedisazodye3Producesblueshadesoncotton-Sulfanilaaideresidue;Subs¬titutednaph-thelenesul-phonicacidresidue-5-chloro-2,6--Substlt

Page 27 - -Bridging

1 (41)Table7tMiscellaneousPyrimidinederivatives2xR R312ColourandSpec,dataUsesRef.Propertiess.fiRRRNO.-HIsthermal2631.Cun)substituted<Cl-6al*yl<ÿ

Page 28 - 165,190

1 (42)RedKeUlCOa*26dpiexazoFastredshadesonleather,proteinfibres,polyialdefibres,polyurethanfibresetc.-Hydroxy-theoxy¬genofwhichlinkedtoaetal-Substitut

Page 29 - Triphenodioxazine

1 (43)5.-H267BrownBrownshades-H-Substitutednaph-thoxazolederivs.-H-Phenyl-Substitutedphenyl268-Hethyl:-Phenyl-Substituted-Hethyl{-Phenyl6.-Substituted

Page 30 - -4,6-difluoro

1 (44)9.-14-Vinyl(4'-styrylbiphenyl))-H-HGoodwhiteningeffectandgoodlightfastnessonpolyesterandpolyatldesubstrates-HTellowFluorescent271Brlghtners

Page 31 - XNH(CH2>&-I

1 (45)13.-Thlo-Methyl-SubstitutedPhenylaxoBactericidalactivity-Methyl276H.-Oxo-H-K-Benwthlaaolcri¬noline;6-*ethyl-quinollne;6-ietho-xy-quinoline;pyri¬

Page 32 - -Sulfanilaaide

1 (46)18.-Hydroxy-Methyl-SubstitutedphenylazoBactericidalactivity-Methyl.-p-iethylphenyl28219.-4-(4'-vinylstilbene)derivs.-Methoxy-KGoodwhitening

Page 33 - C6_1#aryl,C5_i0

1 (47)-H-KYellowDyes283GoldenyellowshadesonpolyesterhavinggoodlightfastnessandrubbingfastnessCjÿalkyl/orphenyl-Substituted-Asaturatedheterocyclicradic

Page 34 - Iaproves

1 (13)dyesusefulInapplicationtopolyester,polyamidesInrecentyearsmanyinnovelasthediazocomponentsorhydroxygroupcontainingorpolyacrylicfibreshavebeendisc

Page 35 - -CHalltyl

1 (48)AimandScopetheAnExtensiveliteratureceP°Ptsareavailablefororganiccolouringcompoundsinparticularthosehavingaheterocyclicmoietysuchasaminopyridines

Page 36 - Xaax*426

1 (49)AimandScapeAnExtensiveliteraturereport*areavailablefortheorganiccolouringcompoundsinparticularheterocyclicmoietysuchasaminopyridines,benzothiazo

Page 37 - -2-tl-Maphtholazo)

1 (50)Amethodforthedeterminationofpurityanddyecontent(azogroup)isdescribed.Thedyesamplesaresubjectedtoreductionwithtitaniumtrichlorideandtheexcesstita

Page 38 - -(4-(Substltuted

1 (51)REFERENCES30C5):55-69(1002).Rangnekar,D.W.1.38(6):48-52(1901).Rangnekar,D.W.2.64BA.BaHoffmann,Johnson,T.B.;Baudisch,O.;3.2629-2631(1931) (Ger.)A

Page 39

1 (52)4pp.CA:Co9B67/26),02Apr.1002.Appl.29Sep.1900,118—149445m(1093).£ur.:Kaletta,B.(BayerA.-G.MilesInc.)12.Wagner.B.J**EP5/0.436(Cl.C09BS7/04),28Oct.

Page 40 - Extensive

1 (53)DE3,738,911(Cl.C09B57/06)24May1989,Appl.17215973r(1989).Nov.1987,14pp,CA:111Offen.DE3,743,20,Frank,G.;Wild,P.(BayerA.-G.)Ger.235(Cl.C09B26/02),2

Page 41 - ,6-Diami

1 (54)(Ciba-GeigyA.-G.)Fur.Pa.t.Appl.EP,*76,Moeck1i.P.28.474(Cl.C09B56/16)02Apr.1986,CHAppl.84/4,018,22Aug.1984,59pp,CA:106-6404p(1987).H.D.(Bayer.A.G

Page 42 - Submicrogram

1 (55)(Chem,Dept.Univ.Minnesota,Minneapolis,MN55455,USA),1ST.J.Chem.1985,25(3-4),264-73(Eng.).37.Adam,J.M.(Ciba-GeigyA.-G.)G*r.Off*n.(Cl.C09B57/00)llO

Page 43 - REFERENCES

1 (56)(1083).45.Lorenz,M.;Schuendehuette,K.H.(Bayer,A—G.)6ÿ.Offen.DE3.215,876,(Cl.C09B67/22),17Mar.1083,DEAppl.3,134,725,02Sep.1981,60pp,CA:09124070m(

Page 44 - 88/1,650,03

1 (57)O//«»v.007,301(Cl.C09B57/04),10Sep.Appl.27Feb.1980,20pp,CAt95Lotsch,W.;Kemper,3,1981,-221295p(1981).'53.R.(BASFA.-G.)Ger.Oy/en,007,10Sep.10

Page 45 - Rangnekar

1 (13)1Aminopyriraidinesmaybecoupledwithdiazotizedaminestogive5-arylazodyes.Although,thecolourrangeofthethroughmonoazodyesthusobtainedarerestrictedtoy

Page 46 - Appl.'

1 (58)I,uxAppl.77,288,09Hay,1077,18pp,CAtQO105634W(1070).62.Ciba-GeigyA.-G.SethAppl.77,13,441,(Cl.C09B29/38),13Jun,1078;Brit.Appl.76/51,462,09Dec.1076

Page 47 - (Ciba-Gelgy

1 (59)f&jJZjJapanKohcti76,140,926(Cl.C09B1/00),Appl.75/64,147,30Hay1975,6pp,(1977).04Dec,1976,CA:ae107999k70.Schefczik,E.(BASFA.—G.)0//en.428,198(

Page 48 - <7//en

1 (60)191326W410,24Sep.1976;26pp,CAi8675/12,Appl.(1977).0//en2,540.R.(Ciba-GelgyA.-G.)Hari,S.;Mory,803CC1.C09B)01Apr.1076,SwissAppl.77.12,572/74,16227

Page 49 - Filmfabrik

1 (61)Soc.1076,55(10),1059-61(Eng.),86.Hee,J.D.(EastmanKodakCo.)U.S,4,026,884(Cl.260-240R;Co9B23/00),31May1977,Jul.1073,15pp,CA:87John,D.(EastmanKodak

Page 50 - Deporter

1 (62)Mellk~Ogandzhanyan,R.G.;Studentsov,E.P.;IvinB.A.(Leningr.Khim-Farm.Inat.197022,Leningrad,USSR)Khirn.G&torotsibl.So&cUn.1988,(5),659-67(R

Page 51 - Off&n

1 (63)(1970).103.Rose,D.;Busch,P•;Lleske,E.(HenkelK.-G.a.A.)671(Cl.Co7D209/08)19Oct.1978,Appl.56337r(1979).Ger.Offen.716,15Apr.1977,18pp,CA:90104,Rose

Page 52 - 78/9,335

1 (64)Ill,Kubersky,H.P,;Rose,D.(HenkelundCleG.m.b.H.)Gor-.2'613*707(Cl.A61K7/13),1Q76*14pp,CA:88-78963C(1078).13Oct.1077*App1.31Mar,112.Kubersky,

Page 53 - Division

1 (65)Appl.75/12,062,22Mar.1975;43pp,CA:866386c(1977).120.DebiMaltreyee(Coll.Scl.Technol.CalcuttaUniv*fCalcutta700009,India)7ndianChem..Sac.1989,66(7)

Page 54 - Patentschrif

1 (66)D06Pl/16).03Jan1060,Appl.76/18,448,05May1676,4165209m(1680).pp,CAt62129.Ghosh,A.P.;Ghosh,K*K.(ShawUniv.)US4,083,841(Cl.260.154;C07C107/04),11Apr

Page 55 - Weinrlch

1 (67)c,0.fOkerulu,I.0.,Okeke,S.I.(Dep.PureInd.136.Okafer,1687,Univ;Nigeria.Nsukka,Nigeria)DyesChem*e8(f),11-24(Eng.).Griffiths,J.137.Cheng,L,;Chen,X.

Page 56 - Dunkelmann

1 (14)position~«J,andalsomadethestructuralconditionsgoverningthecouplingofpyrimidinederivativesandtheirrelationnltrosatiorrÿtothosegoverningManyexampl

Page 57 - Maitreyee

1 (68)1682,GBAppl.60/29,404,11Sep.1080,19pp,CA:077814e(1062).144.Iraal,K.;Mano,M.(TakedaChemicalIndustriesLtd.)fur.Pat.Appl.EP63,9S9(Cl.C07D239/50),02

Page 58 - Industries

1 (69)151.Merck&Co.Inc.Jpn.KoktaiTokkyoKoho78,137.975CC1.C07D239/48),01Dec.1078,App1.77/52,725,10May168647y(1070).1077,6pp,CAsOO152.Vander,Z.;Hlch

Page 59 - Chemical

1 (70)Offen,W.*Herd,K.J.(BayerA.-G.)Ger.159.Reddig,122,100(Cl.C09B62/04)07Jan1093,Appl.04JulyCA:119-29969j(1993).1991,8pp**Offen4,160.Reddig,W.;Herd,K

Page 60 - Patcntschri/

1 (71)Appl.EP513,617(Cl.C09B62/245),19Nov.1992,DEAppl.4,115,622,14May1991;6pp,CA:118214884V(1893).167.Herd,K.J.;Henk,H.:Stoehr,F.M.(BayerEXIT.A.-G.)Pc

Page 61 - Dunkelraann

1 (72)174,Schuendehuette,K.H.*Groll,M.iStawitz,J.w.(BayerA.—G.)EuPat.Appl.EP371,332(Cl.C09B62/26),06Jun1990,DEApp1,3,840,164,29Nov.1988,12pp,CAs114124

Page 62 - Tegtmeyer

1 (73)105pp,CA:11399386s(1990).181.Auerbach.G.;Brenneisen,K.jDoerr,M.;DosvaId,P.;Gisler,M5Koch,W.;Moser,H.A.:Wald,R.(Sando2*tPatentG.m.b.H.)6er.83S,72

Page 63 - Schuendehuette

1 (74)Jun1988,57pp.CAs112236898f<1990).188.Seitz,K.;Hoegerle,K.(Ciba-GeigyA.-G.)£W.PctL.Appl.EP285,571<C1.C09B62/503)05Oct.1988,CHAppl.87/1,258,

Page 64 - Brenneisen

1 (75)G.m.b.H).G.;Moser,H.A.(SandozPatent195*Auerbach,947(Cl.C09B62/245)10Mar1088,DEOffenDE3,728,393961003,630,615.09Sep.1086,SPP,CA:Appl.(1088).Ger.A

Page 65

1 (76)Feb.1988,30Jul1886,12pp,CA:108-206264w(19881.(BayerA.-G.)6«e*r'.203.Jaeger,H.;Herd,K.J.DE3.503,567(Cl.C09B62/25),07Aug.1985,14pp,1986,Appl.

Page 66 - Hoegerle

1 (77)103806d(1987).211.Hibara,T.(MitsubishiChemicalsIndustriesCo.,Ltd.3Jpn.KokaiTokkyoKekoJP62,20,563C8720,5631(Cl.C09B62/17),29Jan.1087,App1.85/158,

Page 67 - Auerbach

1 (15)Table1tBarbituricAcid&derivativesRJv-RRR312R3R45S.RRRColourandSpectraldataUsesRef.KPropertiesNo.1.-Oxo-Oxo-OxoAspigaents8-HBrown-H-fun)subst

Page 68 - Klipper

1 (78)219.Miyamoto,T.,*Omura,T.;Kaneya,Y.fTakeshita.A.?Harada,N.(SumitomoChemicalCoLtd.)Jpn.Kohai*0TokhyoKohoJP208,367[052C8,367D(Cl.C09B62/20319Oct.1

Page 69

1 (79){1OSS}.227.Herd,K.J.;Michna,H.(BayerA.-G.)Offen.340,274(Cl.C09B62/02),15May1985,DE3.App1.08NOV.1083,37pp,CA:103197368a(1985).228.Raue,RWunderlic

Page 70

1 (80)OSfen.DE3.216,787(Cl.C09B62/008),10Nov.1983,Appl.05May1988,42pp,CA;lOO-(Bayer*.-G.)Ger.Offen.3.145,728(Cl.53196h(1984).236.Henk,HC09B62/032),26H

Page 71 - Wunderlich

1 (81)80/9,302,17Dec.1080,52pp,CA:07146210t(1982).244.Jaeger,H.jD11zer,R.CBayerA.G.)6er.Offen,DE3,21Jan.1082,Appl.26144462g(1082).023,920(Cl.C09B62/02

Page 72 - Schuendehuet

1 (82)C09B62/09S),07Jan1981,Ger.Appl.2.925,942,27Jun1979,26pp,CA:94253,Schuendehuette,K.H.;Moll,193699g(1981).R.;Nichel,H.;Scholl,W.(BayerA.-G.)Ger.Of

Page 73

1 (83)261.Boehmke,G.fHendricks>U.W.;Hildebrand,D.tBayerA.G«)Ger.tf-n£,832,214(ClD06P5/02),31Jan.1980,App1.21Jul.1978,15pp,CA:92182495V(1980).262.Ku

Page 74

1 (84)1985,<52(3),229-30(Eng.).Techno1.269.Padmanabhan,S.jSheshadri,S.(Dep.Chem.1685Pigm.UnlvBombay.Bombay400019.India).£?ye£*r6(6),397-403(Eng.)Of

Page 75 - Hildebrand

1 (85)276,NlgairwS.C.;Saharia,G.S.jSharma,H.R.(Dep,Chem.Unlv.Delhi,Delhi110007.India)Chem.Soc.Indian1983,©0(6),583-4(Eng.).277.Levkoeva,E.I.;Aleksandr

Page 76 - Correction

1 (86)204.Rolf,M«iNeeff,R•IMuller,W.(BayerA.-G.)Ger.OffenC09B56/12),09Sep.1082,Appl.DE3,106,358(Cl.20Feb.4981,31pp,Burdeska,KCA:97-218032m(1082).285.K

Page 77 - Sve3hnikov

1 (16)Anionicazodye16Showsgoodwatersolubility,lowfoaaingandlowcorrosivitytodyeingapplication-H-H-Oxo5-.-Oxo-OxoPigaents17YellowProducesyellowcolourtop

Page 78 - Herbert

1 (17).12.-Oxo-Oxo-Oxo-H-H-Thio--Aiino-'CM_-cyanl-alkyl-aiino-Anno--(un)substi--Cj_4-tutedalkyl;alkyl-(un)substi-ailnotutedphenyl-(un)substi--Sub

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